Who wins?
Frieza vs Pain
Frieza wins 53% to 47%. 19 more put them in the same row. From Iconic Anime Villains Tier List. Pick a side.
ChrisPlays on Frieza: killed Krillin and created the first Super Saiyan, the original
badgerguy82 on Pain: the Pain arc is peak Naruto
Iconic Anime Villains Tier List: the full ranking