Who wins?
Pain vs Dio Brando
Pain wins 56% to 44%. 20 more put them in the same row. From Iconic Anime Villains Tier List. Pick a side.
badgerguy82 on Pain: the Pain arc is peak Naruto
CrispyOtter on Dio Brando: he stole Jonathan's body and came back a century later, that's commitment
Iconic Anime Villains Tier List: the full ranking